I am actually a licensed bait dealer that traps and transports Spottail shiners and before I even finished reading your post I thought “Shiner Life” or “Sure Life” treatment for sure.
As for your PH levels they will be handled by your treatments. I handle truckloads of shiners and massive tanks full of them and have never had to touch the ph levels or do I truly know the exact levels. What are you using for a water supply? Well or city? If you are trying to use city water you have a HUGE chore getting rid of all the additives put into public water. Another thing to make sure is your water does not go through a softener before hand, that will mess with the works if the brine does not cleanly purge. Cheaper softener systems turn your tanks into saltwater units.
As for shiners and most other species of native minnows they will keep better in very cool water and do not crowd them. In Minnesota a non commercial licensed person may not posses more than 12 dozen minnows at any time so that should not be a problem in a big freezer. Not sure how other states write possession laws for bait.
What will get you in trouble is ammonia. Minnows do their duty in the water and create high amounts of ammonia. Best remedy is to have a turbine style agitator that bubbles the water and releases the bad stuff along with a lot of flow leaving the tank. To give you an idea our smaller 500 gallon tanks have a stream of water the size the pencil feeding into them 24/7 to keep it cool and keep it clean. And never ever close the top off. Another thing you will have a heck of time with is tank cleaning. That scum line that builds up is the bad stuff that has dried on the tank; the underwater version you do not see is even worse as it rots and raises heck with your water condition. We have to clean our tanks every four- five days for shiners.
And the number one thing that will knock out your supply is dead ones. If you have a few floaters they need to come out ASAP as once they die they turn into tank poison.
Shiners are a pain in the butt. Emeralds are the worst, Spottails are a close second, goldies are a little tougher and river shiners could live in a toilet…as could fatheads and creek chubs. What species are you looking to hold mostly as they each have bad habits? Suckers rub their face off, creek chubs hit their mouth on the tank and get sick, fatheads get fungus, bullheads and Mad Toms secrete some type of bad stuff etc etc.